Kessler, Vadim
- Institutionen för molekylära vetenskaper, Sveriges lantbruksuniversitet
Sammanfattning
This chapter summarizes modern approaches in the synthesis of metal alkoxides, provides an overview of their physical and chemical properties, with a special focus on molecular structure and reactivity, and gives a brief but up-to-date presentation of the reaction mechanisms in the synthesis of inorganic materials from metal alkoxides as precursors (alkoxosynthesis). A critical overview of molecular precursor approaches exploiting homo- and heteroleptic alkoxide complexes is provided, explaining the role of heteroligands in nucleation and subsequent growth of the resulting nanostructured materials. This chapter also provides a brief summary of other principal applications of metal alkoxides, such as homogeneous catalysts and molecular magnets, with a special focus on the synthesis and structure of these functional molecules.
Publicerad i
Titel: Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications
Utgivare: Elsevier
SLU författare
UKÄ forskningsämne
Oorganisk kemi
Materialkemi
Publikationens identifierare
- DOI: https://doi.org/10.1016/B978-0-08-097774-4.00220-5
- ISBN: 978-008096529-1
Permanent länk till denna sida (URI)
https://res.slu.se/id/publ/61957