The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

Abstract

interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved

Keywords

Iron oxo-ethoxide; Mass-spectrometry; X-ray study; Sol–gel

Published in

Inorganica Chimica Acta
2005, volume: 358, number: 12, pages: 3506-3512
Publisher: ELSEVIER SCIENCE SA

SLU Authors

• Seisenbaeva, Gulaim

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

• Gohil, Suresh

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

• Kessler, Vadim

  • Department of Molecular Sciences, Swedish University of Agricultural Sciences
    

Publication identifier

• DOI: https://doi.org/10.1016/j.ica.2005.03.048

Permanent link to this page (URI)

https://res.slu.se/id/publ/7993